Investigation of the electrical properties of a new PPV derivative-based on a sandwich structure for opto-electronic applications

The opto-electronic properties of native poly(p-phenylene vinylene) (PPV) were tuned by the confinement of the π-conjugation and the incorporation of a sulphur group as a spacer in order to obtain a blue-green emitting polymer (PPVS). The energy band gap of the PPVS thin film has been measured by UV-vis absorption spectroscopy and evaluated to 2.87 eV. Current-voltage characteristics and impedance spectroscopy measurements performed on sandwich structures [ITO/PPVS/Al] are used to elucidate the conduction mechanisms. The static electrical characterisations showed a space charge limited conduction (SCLC) and a conductivity with low power frequency behaviour characteristic of a hopping transport in disordered materials. The impedance spectra can be discussed in terms of an equivalent circuit model designed as a parallel resistor R_P and capacitor C_P network in series with a resistor R_S. We extract numerical values of these parameters by fitting experimental data. Their evolution with bias voltages has shown that the SCLC mechanism is characterised by an exponential trap distribution.     

象山港黄墩支港菲律宾蛤仔种群COI和ITS1基因序列特征及遗传多样性分析

为了解象山港黄墩支港菲律宾蛤仔种质资源的遗传多样性现状, 采用COI和ITS1分子标记对该种群进行了基因序列特征和遗传多样性分析. 结果表明 在该种群30个个体中扩增得到的COI基因序列长度均为709bp, ITS1序列长度范围在693~729bp(共有746个位点). COI基因序列的位点中有670个保守位点(占94.50%)、39个变异位点(占5.50%); ITS1序列的位点中有保守位点671个(占89.95%)、变异位点62个(占8.31%)和缺失/插入位点13个(占1.74%). COI基因序列的保守性高于ITS1序列. 在COI基因序列中碱基(A+T)的占比(65.84%)高于(C+G), 而ITS1序列中则是碱基(A+T)占比(37.59%)低于(C+G). COI和ITS1序列的遗传距离分析均显示群体内遗传分化不明显. 基于COI基因序列和ITS1序列构建的遗传进化树显示 各科贝类分别相聚, 象山港菲律宾蛤仔位于帘蛤科的分支中, 其COI序列与杂色蛤进化关系最近. 遗传进化树中各种贝类的聚类关系与传统分类学结果相一致, 可作为分类的参考. COI和ITS1序列的平均核苷酸差异数分别为5.497和6.549, 核苷酸多样性指数分别为0.00775和0.00973, 单倍型数目分别为21和28, 单倍型多样性分别为0.963和0.993, 根据COI和ITS1两个序列计算得到的菲律宾蛤仔象山港群体单倍型多样性均大于0.5, 核苷酸多样性指数均大于0.005, 表明该种群遗传多样性丰富, 并处于稳定状态. 本研究结果补充了菲律宾蛤仔遗传多样性方面的研究资料, 并可为象山港菲律宾蛤仔种质资源保护和遗传育种提供理论基础.     

Dynamics of ellipsoidal cavities in fluid

A mathematical model of the hydrodynamics of free closed surfaces in a fluid is expounded. It is used for studying the dynamics of ellipsoidal cavities during their development. The model is based on a system of differential equations that accounts for the influence exerted on the dynamics of cavities by various perturbations such as gravity, surface tension, viscosity, and geometrical features of the cavity. Solving this system makes it possible to determine the hydrodynamic characteristics of the flow around the cavity and to plot cavity shapes depending on time and flow regimes. Characteristic features of the development of such cavities under gravity and surface tension are established __________ Translated from Prikladnaya Mekhanika, Vol. 42, No. 2, pp. 24–31, February 2006.     

Influence of the coupling of mechanical and thermal fields on the amplitude-frequency characteristics of a cylinder

A dynamic boundary-value problem of coupled thermoelasticity for a finite cylinder with mixed boundary conditions is solved. The problem is reduced to a system of four singular integral equations solved by the mechanical-quadrature method. A numerical experiment is conducted to obtain amplitude-frequency characteristics for finite cylinders with different cross sections. The effect of thermoelastic coupling on stress distribution is assessed __________ Translated from Prikladnaya Mekhanika, Vol. 42, No. 10, pp. 86–95, October 2006.     

双螺杆转子的受力分析

从双螺杆转子螺旋曲面的参数方程出发，利用空间解析几何理论将转子三维螺旋面坐标映象为对应不同压力腔的二维积分区域，在整个积分区域积分可以计算作用在双螺杆压缩机，双螺杆泵螺旋面转子上的力和力矩。本文以一种双螺杆泵的转子为例，利用本方法进行了受力分析，解析出转子受力，力矩随转子转角的变化关系。     

二维系统传递矩阵法

以薄板横向振动的振动特性问题为例提出了二维系统传递矩阵法. 从质点和无质量梁的传递 矩阵出发，建立了按列排列的薄板子结构的传递矩阵. 用二维系统传递矩阵法获得了整个板 的总体传递方程，从而可得到板在任意一种边界条件下的特征方程. 数值求解了两种情况下 薄板横向振动的固有振动特性. 计算结果表明，用该方法可用于研究类似薄板的二维系统的 动力学问题，且无需建立系统的总体动力学方程.     

氮离子注入钴烧结碳化钨的综合性能考察

本文对剂量为1.5×10~(17)、2.0×10~(17)和2.5×10~(17)Natoms/cm~2的3种氮离子注入钴烧结碳化钨表层的元素深度分布,显微硬度和摩擦学特性,以及氮离子注入改性的断续切削刀具之切削性能和使用寿命进行了考察,并就氮离子注入表面改性机理作了探讨。作者指出,钴烧结碳化钨经氮离子注入改性后可以减少1Cr18Ni9Ti不锈钢材料在干滑动摩擦时的粘附转移,并能使低摩擦力的摩擦初始段延长;适量的氮离子注入可以提高钻烧结碳化钨的表层硬度,而过量的注入却又会导致硬度下降;适量的氮离子注入可以减少钻烧结碳化钨刀具的切削刃部在使用过程度中的粘屑和崩刃,能够明显地提高刀具的切削性能和使用寿命。     

码头动力特性现场测试方法研究

码头的动力特性的变化直接影响到码头的安全运行。实测码头的动力特性具有重要意义。通过四种不同的现场检测方法的研究和分析，确定了不同方法的使用范围。说明现场检测的方法可以有效地确定码头的动力特性。     

区间桁架结构动力特性分析的区间因子法

对于具有区间参数的桁架结构的动力特性分析问题,提出了一种新的分析方法即区间因子法。利用区间因子法,结构材料物理参数、几何尺寸均可表达为其区间因子和确定性量的乘积,进而结构的固有频率和振型也可显式表达成区间因子们的函数。利用区间算法,推导出了结构固有频率和振型的上、下限与均值的计算表达式。通过算例,分析了结构参数的不确定性对结构动力特性的影响,并验证了本文模型和方法的合理性与可行性。本文方法的优点是能够反映结构某一参数的不确定性对结构动力特性的影响。